Alevel物理真题解析:热力学简答题(ideal gas、internal energy等)

接触到热力学(Thermal physics),会从微观粒子(particles或molecules)的角度来解释物质的温度、压强、动能、势能等问题。学生们会觉得微观的部分不太好理解,知识点可以理解,落实到练习题,仍然会有下不了手的感觉。

今天我们整理并分享几道ideal gas(理想气体)相关的简答题。通过这几题辅助大家思考一下理论知识点和考题的联系。

试题来源:CAIE A Level物理(9702)近年真题

问题1:What is meant by an ideal gas.

解析:

这是一道基础的定义题,解释什么是ideal gas。

简单来说只要符合ideal gas equation,pV / T = constant的,就叫理想气体。

不过要同时解释清楚p、V和T分别代表哪些物理量。

答案:

ž gas obeys formula pV / T = constant

ž p is pressure

ž V is volume

ž T is kelvin temperature

问题2:An ideal gas is said to consist of molecules that are hard elastic identical spheres. State two further assumptions of the kinetic theory of gases.

解析:

问题要求写两点关于kinetic theory of gas的假设。

假设一共有好多条,大致可以整理成6条,这几条是后面理解kinetic theory equation的推导和有关理想气体internal energy相关问题的重要前提。

答案:

6选2,优先选择前面几条答案。

ž total volume of molecules negligible compared to that of container

ž no intermolecular forces/ no forces between molecules (except during collisions)

ž molecules in random motion

ž all collisions involving molecules of the gas are elastic

ž time of collision small compared with the time between collisions

ž large number of molecules

问题3:One of the assumptions of the kinetic theory of gases is related to the volume of the atoms.

解析:

本题是由上述6条假设延伸出的问题,要求我们写有关粒子体积的那一条假设。

答案:

assumption: volume of atoms negligible compared to volume of container

问题4:ΔU = (+q) + (+w) 热力学第一定律这几个字母所代表的含义。

解析:

ΔU指的是内能(internal energy)的变化,如果internal energy增加,那ΔU是正的;如果internal energy减少,那ΔU是负的。

q代表这个系统吸收thermal energy或者释放thermal energy。

w代表work done,做功,是对系统做功还是系统对外做功。

答案:

ž +ΔU : the increase or decrease in internal energy of the system

ž -ΔU decrease in internal energy of the system

ž +q:thermal energy transfer to system

ž + w:work done on system

问题5:State what is meant by the internal energy of a system.

解析:

Internal energy的定义,指的是组成物质的particles所具有的动能和势能的总和。

U=Σk.e.+Σp.e.

答案:

ž sum of potential energy and kinetic energy (of particles)

ž (total) energy of random motion of particles

问题6:By reference to intermolecular forces, explain why the change in internal energy of an ideal gas is equal to the change in total kinetic energy of its molecules.

解析:

通过讨论分子间作用力来解释内能的变化=总动能的变化。

内能公式:U=Σk.e.+Σp.e.;要想ΔU=ΔΣk.e.,那么Σp.e.必须等于0

再结合kinetic theory of ideal gas的假设,粒子之间没有分子间作用力,所以也没有potential energy。

整理一下思路得到下面答案。

答案:

ž (in ideal gas,) no intermolecular forces

ž no potential energy

ž so change in kinetic energy is change in internal energy

问题7:Use one of the assumptions of the kinetic theory of gases to explain why the potential energy of the molecules of an ideal gas is zero.

解析:

和问题6是类似的问题,答案只需要写到potential energy=0就可以了。

答案:

ž no intermolecular forces (so no potential energy)

问题8:Explain why, for an ideal gas, the change in internal energy is directly proportional to the change in thermodynamic temperature of the gas.

解析:

这也是一道有关内能公式的延伸问题。

解释ΔU和热力学温度成正比,而温度和k.e.成正比,也就是ΔU和k.e.成正比,那么就回到了问题6。

自然就得到下面的答案。

答案:

ž (in ideal gas) no intermolecular forces so no potential energy

ž internal energy is (solely) sum of kinetic energy (of particles)

ž (mean) kinetic energy (of particles) proportional to (thermodynamic) temperature of gas

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